Plumeria alba flower extract-mediated synthesis of recyclable chitosan-coated cadmium nanoparticles for pest control and dye degradation.

In the current scenario, many synthetic chemicals have used long-term to control pests and mosquitoes, leading to the resistance of strains and toxicity effect on human beings. To overcome the adverse problem in recent advances, the scientific community is looking into nanofabricated pesticides and mosquitoes. This study aims to synthesize the recyclable chitosan-coated cadmium nanoparticles (Ch-CdNps) using Plumeria alba flower extract, which was further applied for insecticidal and mosquitocidal activities. The synthesized Ch-CdNps were confirmed by UV spectroscopy and FTIR analysis. The XRD, TEM, and DLS results confirmed the crystallinity with a spherical shape at 80-100 nm. The insecticidal activity proves that Ch-CdNps inhibited Helicoverpa armigera and Spodoptera litura at 100 ppm. In mosquitocidal, LC50 values of larvicidal of 1st instar were 4.116, 4.33, and 4.564 µg/mL, and the remaining three stages of instars, pupicidal, adulticidal, longevity, fecundity, and ovicidal assays inhibit the Anopheles stephensi followed by Aedes aegypti and Culex quinquefasciatus. Further, the first-order kinetics of photocatalytic degradation of methylene blue and methyl orange was confirmed. Based on the obtained results, Ch-CdNps can inhibit the pest, mosquitoes, and photocatalytic degradation.

Lonar lake, India: an impact crater in basalt.

Discovery of shock-metamorphosed material establishes the impact origin of Lonar Crater. Coarse breccia with shatter coning and microbreccia with moderately shocked fragments containing maskelynite were found in drill holes through the crater floor. Trenches on the rim yield strongly shocked fragments in which plagioclase has melted and vesiculated, and bombs and spherules of homogeneous rock melt. As the only known terrestrial impact crater in basalt, Lonar Crater provides unique opportunities for comparison with lunar craters. In particular, microbreccias and glass spherules from Lonar Crater have close analogs among the Apollo specimens.